Portgas D. Ace is the biological son of Portgas D. Rouge and Gol D. Roger.
He was born as Gol D. Ace and the adopted brother of Sabo and Luffy.
He was adopted by Monkey D. Garp as wished by Roger to him before his birth.
Ace was the 2nd division commander of the Whitebeard Pirates and one-time captain of the Spade Pirates.
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